A function is called a linear transformation if:
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The function preservers linear combinations.
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Property is called homogeneity.
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Property is called superposition.
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Since every matrix transformation preserves linear combinations, every matrix transformation is a linear transformation.
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A linear tf is a matrix tf it it can be represented as a matrix-vector product and Theorem 32.2 - every linear transformation has a corresponding matrix transformation
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I.e. a tf is linear iff it is also a matrix tf.